Indane Based Molecular Motors: UV-Switching Increases Number of Isomers
We describe azophenylindane based molecular motors (aphin-switches) which have two different rotamers of -configuration and four different rotamers of -configuration. The behaviors of these motors were investigated both experimentally and computationally. The conversion of aphin-switch does not yield single isomer but a mixture of these. Although the to conversion leads to the increase of the system entropy some of the -rotamers can directly convert to each other while others should convert via -configuration. The motion of aphin-switches resembles the work of a mixing machine with indane group serving as a base and phenol group serving as a beater. The aphin-switches presented herein may provide a basis for promising applications in advanced biological systems or particularly in cases where on demand disordering of molecular packing has value, such as lipid bilayers.
: 36235252
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- - (February 12, 2020 December 31, 2022). . Grant, RFBR.


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